【英文标准名称】:StandardTestMethodsforChemicalAnalysisofCeramicWhitewareMaterialsUsingWavelengthDispersiveX-RayFluorescenceSpectrometry
【原文标准名称】:使用波长色散X射线荧光光谱法进行白色陶瓷材料化学分析的标准试验方法
【标准号】:ASTMC1605-2004(2009)
【标准状态】:现行
【国别】:美国
【发布日期】:2004
【实施或试行日期】:
【发布单位】:美国材料与试验协会(US-ASTM)
【起草单位】:C21.03
【标准类型】:(TestMethod)
【标准水平】:()
【中文主题词】:
【英文主题词】:Ceramicwhitewares;Chemicalanalysis;Spectrometry;WavelengthdispersiveX-rayfluorescence(WDXRF)
【摘要】:1.1Thesetestmethodscoverthedeterminationoftenmajorelements(SiO2,Al2O3,Fe2O3,MgO,CaO,Na2O,K2O,TiO2,P2O5,MnO,andLOIinceramicwhitewaresclaysandmineralsusingwavelengthdispersiveX-rayfluorescencespectrometry(WDXRF).Thesampleisfirstignited,thenfusedwithlithiumtetraborateandtheresultantglassdiscisintroducedintoawavelengthdispersiveX-rayspectrometer.ThediscisirradiatedwithX-raysfromanX-raytube.X-rayphotonsemittedbytheelementsinthesamplesarecountedandconcentrationsdeterminedusingpreviouslypreparedcalibrationstandards.(1)Inadditionto10majorelements,themethodprovidesagravimetricloss-on-ignition.Note18212;MuchofthetextofthistestmethodisderiveddirectlyfromMajorelementanalysisbywavelengthdispersiveX-rayfluorescencespectrometry,includedinRef(1).1.2Interferences,withanalysisbyWDXRF,mayresultfrommineralogicalorotherstructuraleffects,lineoverlaps,andmatrixeffects.Thestructureofthesample,mineralogicalorotherwise,iseliminatedthroughfusionwithasuitableflux.Fusionofthesamplediminishesmatrixeffectsandproducesastable,flat,homogeneoussampleforpresentationtothespectrometer.Selectingcertaintypesofcrystalmonochromatorseliminatesmanyofthelineoverlapsandmultiorderlineinterferences.Amathematicalcorrectionprocedure(2)isusedtocorrectfortheabsorptionandenhancementmatrixeffects.1.3Concentrationsoftheelementsinclaysandmineralsaredeterminedindependentoftheoxidationstateandarereportedintheoxidationstateinwhichtheymostcommonlyoccurintheearthx2019;scrust.
【中国标准分类号】:Q32
【国际标准分类号】:71_040_50
【页数】:5P.;A4
【正文语种】:英语